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A plot has to be open for this to work. The plot will be redrawn.
In SPECX 6.3 I didn't find any equivalent for horizontal lines, but if you really want to do this, one method that works is to multiply your spectrum by zero number, offset to where you want it vertically, and replot the spectrum. Thus, say:
mult 0.0; off 2.5; over 1 6
would put a horizontal line on your open plot 2.5 K above zero. This also allows one ready control over both line width and color. SPECX 6.7 includes the baseline command which implements this sequence for you.
Specx Cookbook Reduction of millimetre wave data